Journal of Advances in Environmental Health Research

Journal of Advances in Environmental Health Research

Adsorption of 4-chlorophenol from aqueous solution using activated carbon synthesized from aloe vera green wastes

Document Type : Original Article

Authors
Yusef Omidi-Khaniabadi 1
Ali Jafari 1
Heshmatollah Nourmoradi 2
Fatemeh Taheri 1
Seddigheh Saeedi 1
1 Department of Environmental Health Engineering, School of Health, Lorestan University of Medical Sciences, Khorramabad, Iran
2 Department of Environmental Health Engineering, School of Health, Ilam University of Medical Sciences, Ilam, Iran
10.22102/jaehr.2015.40194
Abstract
In this study, activated carbon synthesized from Aloe vera green wastes was used as a sorbent to remove 4-chlorophenol (4-CP) from aqueous solutions. The influence of contact time (0-100 minutes), pH (2-8), adsorbent dosage (1-9 g/l), and initial 4-CP concentration (10-60 mg/l) in batch system was investigated on the sorption. The sorbent was specified using scanning electron microscopy (SEM). Equilibrium for 4-CP sorption was reached at contact time of 40 minutes. The pH of 2 was also found to be the optimum pH in the sorption process. Fitting the experimental data to different kinetic and isotherm models illustrated that the experimental data was well fitted by pseudo-second order kinetic (R2 > 0.98) and Freundlich isotherm (R2 > 0.99) models. According to the results, activated carbon prepared from Aloe vera green wastes is a low-cost effective option for the sorption of 4-CP from aqueous solutions.
Keywords
Adsorption
Aloe vera
4-Chlorophenol
Kinetics
  1. Jourvand M, Shams Khorramabadi G, Omidi Khaniabadi Y, Godini H, Nourmoradi H. Removal of methylene blue from aqueous solutions using modified clay. Journal of Basic Research in Medical Sciences 2015; 2(1): 32-41.
  2. Nguyen AT, Juang RS. Photocatalytic degradation of p-chlorophenol by hybrid H(2)O(2) and TiO(2) in aqueous suspensions under UV irradiation. J Environ Manage 2015; 147: 271-7.
  3. Nourmoradi H, Avazpour M, Ghasemian N, Heidari M, Moradnejadi K, Khodarahmi F, et al. Surfactant modified montmorillonite as a low cost adsorbent for 4-chlorophenol: Equilibrium, kinetic and thermodynamic study. Journal of the Taiwan Institute of Chemical Engineers 2015.
  4. Sun Y, Chen J, Li A, Liu F, Zhang Q. Adsorption of resorcinol and catechol from aqueous solution by aminated hypercrosslinked polymers. Reactive and Functional Polymers 2005; 64(2): 63-73.
  5. Ahmed MJ, Theydan SK. Adsorption of p-chlorophenol onto microporous activated carbon from Albizia lebbeck seed pods by one-step microwave assisted activation. Journal of Analytical and Applied Pyrolysis 2013; 100: 253-60.
  6. Sze MF, McKay G. An adsorption diffusion model for removal of para-chlorophenol by activated carbon derived from bituminous coal. Environ Pollut 2010; 158(5): 1669-74.
  7. Sze MF, McKay G. Enhanced mitigation of para-chlorophenol using stratified activated carbon adsorption columns. Water Res 2012; 46(3): 700-10.
  8. Dominguez-Vargas JR, Navarro-Rodriguez JA, de Heredia JB, Cuerda-Correa EM. Removal of chlorophenols in aqueous solution by carbon black low-cost adsorbents. Equilibrium study and influence of operation conditions. J Hazard Mater 2009; 169(1-3): 302-8.
  9. Zhihui A, Peng Y, Xiaohua L. Degradation of 4-chlorophenol by microwave irradiation enhanced advanced oxidation processes. Chemosphere 2005; 60(6): 824-7.
  10. Sarkar M, Acharya PK. Use of fly ash for the removal of phenol and its analogues from contaminated water. Waste Manag 2006; 26(6): 559-70.
  11. Nourmoradi H, Nikaeen M, Khiadani H. Removal of benzene, toluene, ethylbenzene and xylene (BTEX) from aqueous solutions by montmorillonite modified with nonionic surfactant: Equilibrium, kinetic and thermodynamic study. Chemical Engineering Journal 2012; 191: 341-8.
  12. Babaei AA, Alaee Z, Ahmadpour E, Ramazanpour-Esfahani A. Kinetic modeling of methylene blue adsorption onto acid-activated spent tea: A comparison between linear and non-linear regression analysis. Journal of Advances in Environmental Health Research 2014; 2(4): 197-208.
  13. de Luna MD, Flores ED, Genuino DA, Futalan CM, Wan MW. Adsorption of Eriochrome Black T (EBT) dye using activated carbon prepared from waste rice hulls??Optimization, isotherm and kinetic studies. Journal of the Taiwan Institute of Chemical Engineers 2013; 44(4): 646-53.
  14. Dehestaniathar A, Rezaee A. Adsorption of nitrate from aqueous solution using activated carbon-supported Fe0, Fe2 (SO4)3, and FeSO4. Journal of Advances in Environmental Health Research 2014; 2(3): 181-8.
  15. Bilgili MS. Adsorption of 4-chlorophenol from aqueous solutions by xad-4 resin: isotherm, kinetic, and thermodynamic analysis. J Hazard Mater 2006; 137(1): 157-64.
  16. Kuleyin A. Removal of phenol and 4-chlorophenol by surfactant-modified natural zeolite. J Hazard Mater 2007; 144(1-2): 307-15.
  17. Gomez M, Matafonova G, Gomez JL, Batoev V, Christofi N. Comparison of alternative treatments for 4-chlorophenol removal from aqueous solutions: use of free and immobilized soybean peroxidase and KrCl excilamp. J Hazard Mater 2009; 169(1-3): 46-51.
  18. Li JM, Meng XG, Hu CW, Du J. Adsorption of phenol, p-chlorophenol and p-nitrophenol onto functional chitosan. Bioresour Technol 2009; 100(3): 1168-73.
  19. Akbal F. Sorption of phenol and 4-chlorophenol onto pumice treated with cationic surfactant. J Environ Manage 2005; 74(3): 239-44.
  20. Abburi K. Adsorption of phenol and p-chlorophenol from their single and bisolute aqueous solutions on Amberlite XAD-16 resin. J Hazard Mater 2003; 105(1-3): 143-56.
  21. Koumanova B, Peeva-Antova P. Adsorption of p- chlorophenol from aqueous solutions on bentonite and perlite. J Hazard Mater 2002; 90(3): 229-34.
  22. Zazouli M, Balarak D, Mahdavi Y. Application of Azolla for 2-Chlorophenol and 4-Chrorophenol Removal from Aqueous Solutions. Iranian Journal of Health Sciences 2013; 1(2): 43-55.
  23. Malakootian M, Mansoorian HJ, Yari A. Removal of reactive dyes from aqueous solutions by a non-conventional and low cost agricultural waste: adsorption on ash of Aloe Vera plant. Iranian Journal of Health, Safety & Environment 2014; 1(3): 117-25.
  24. Liu Q, Yang B, Zhang L, Huang R. Adsorption of an anionic azo dye by cross-linked chitosan/bentonite composite. Int J Biol Macromol 2015; 72: 1129-35.
  25. Karaca S, G?rses A, Acisli O, Hassania A, Kiransan M, Yikilmaz K. Modeling of adsorption isotherms and kinetics of Remazol Red RB adsorption from aqueous solution by modified clay. Desalination & Water Treatment 2013; 51(13-15): 2726-39.
  26. Chen D, Chen J, Luan X, Ji H, Xia Z. Characterization of anion???cationic surfactants modified montmorillonite and its application for the removal of methyl orange. Chemical Engineering Journal 2011; 171(3): 1150-8.
  27. Chaari I, Feki M, Medhioub M, Bouzid J, Fakhfakh E, Jamoussi F. Adsorption of a textile dye "Indanthrene Blue RS (C.I. Vat Blue 4)" from aqueous solutions onto smectite-rich clayey rock. J Hazard Mater 2009; 172(2-3): 1623-8.
  28. Tseng RL, Tseng SK. Pore structure and adsorption performance of the KOH-activated carbons prepared from corncob. J Colloid Interface Sci 2005; 287(2): 428-37.
  29. Wu FC, Tseng RL, Hu CC. Comparisons of pore properties and adsorption performance of KOH-activated and steam-activated carbons. Microporous and Mesoporous Materials 2005; 80(1?3): 95-106.
  30. DiazGomez-Trevino AP, Martinez-Miranda V, Solache-Rios M. Removal of remazol yellow from aqueous solutions by unmodified and stabilized iron modified clay. Applied Clay Science 2013; 80?81: 219-25.
  31. Laszlo K. Adsorption from aqueous phenol and aniline solutions on activated carbons with different surface chemistry. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2005; 265(1?3): 32-9.
  32. Radhika M, Palanivelu K. Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbent?Kinetics and isotherm analysis. Journal of Hazardous Materials 2006; 138(1): 116-24.
  33. Almeida CA, Debacher NA, Downs AJ, Cottet L, Mello CA. Removal of methylene blue from colored effluents by adsorption on montmorillonite clay. J Colloid Interface Sci 2009; 332(1): 46-53.
  34. Radaee E, Alavi Moghaddam MR, Arami M. The Study of the Adsorption of Reactive Blue 19 Dye by Activated Carbon from Pomegranate Residue. Journal of Water & Wastewater 2014; 25(92): 27-34.
  35. Noorimotlagh Z, Darvishi Cheshmeh Soltani R, Khataee AR, Shahriyar S, Nourmoradi H. Adsorption of a textile dye in aqueous phase using mesoporous activated carbon prepared from Iranian milk vetch. Journal of the Taiwan Institute of Chemical Engineers 2014; 45(4): 1783-91.
  36. Elmoubarki R, Mahjoubi FZ, Tounsadi H, Moustadraf J, Abdennouri M, Zouhri A, et al. Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics. Water Resources and Industry 2015; 9: 16-29.
  37. Ghaedi M, Khajesharifi H, Hemmati Yadkuri A, Roosta M, Sahraei R, Daneshfar A. Cadmium hydroxide nanowire loaded on activated carbon as efficient adsorbent for removal of Bromocresol Green. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012; 86: 62-8.
  38. AL-Doury MM, Ali SS. Removal of Phenol and Parachlorophenol from Synthetic Wastewater Using Prepared Activated Carbon from Agricultural Wastes. International Journal of Sustainable and Green Energy 2015; 4(3): 92-101.
  39. Mouruo PAM, Carrott PJM, Ribeiro Carrott MML. Application of different equations to adsorption isotherms of phenolic compounds on activated carbons prepared from cork. Carbon 2006; 44(12): 2422-9.
Journal of Advances in Environmental Health Research
Volume 3, Issue 2 - Serial Number 2
9
Summer 2015
Pages 120-129