Journal of Advances in Environmental Health Research

Journal of Advances in Environmental Health Research

Removal of COD and TOC From Petroleum Synthetic Wastewater Containing Cyclic Aromatic Hydrocarbons Using the Photo-Fenton Process by the Box-Behnken Method

Document Type : Original Article

Authors
Goharol-Sharieh Barati 1
Seyed Mehdi Borghei 1, 2
Reza Jalilzadeh Yengejeh 1
Afshin Takdastan 1, 3, 4
1 Department of Environmental Engineering, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
2 Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran
3 Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
4 Environmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
10.34172/jaehr.2023.09
Abstract
Background: In the last few decades, concern over environmental safety has increased significantly. One of the main causes of environmental degradation is the discharge of untreated pollutants into water bodies. This study examined the efficiency of the photo-Fenton oxidation process to remove chemical oxygen demand (COD) and total organic carbon (TOC) from petroleum wastewater.
Methods: Experiments were designed using the Box-Behnken method- a model of the response surface method (RSM) by MINITAB software. First, a wooden chamber equipped with UV lamps installed in the center was applied. The effect of effective parameters on the photo-Fenton process, including naphthalene concentration (10-70 μg/L), pH (2-7), H2O2 (50-800 mg/L), Fe (5-80 mg/L), contact time (10-120 minutes) and UV rays was investigated.
Results: The highest removal efficiency of the COD (case 89.27) was at achieved at pH = 2, UV = 24, naphthalene concentration 10 μg/L, Fe concentration 36.06 mg/L, hydrogen peroxide content 800 mg/L, and contact time 120 min. Besides, the highest removal efficiency of the process in removing TOC was 71.04% obtained at 2 pH = 24, UV = 24, and a reaction time of 120 min.
Conclusion: Based on the results of this research, the photo-Fenton process has a significant efficiency in removing COD and TOC from petroleum effluents containing cyclic aromatic hydrocarbons and can be utilized as an efficient method for the treatment of petroleum wastewaters.
Keywords
Naphthalene
Advanced oxidation process
COD
TOC
Photo-Fenton
Petroleum effluent

Subjects

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Journal of Advances in Environmental Health Research
Volume 11, Issue 2
Spring 2023
Pages 72-81